We work on the development of new organic semiconducting polymer materials and their application to organic electronic devices. Specifically, relying on the basic chemistry of the intermolecular interactions during the film forming process from the solutions, we seek the methodology and the molecular design to control the precise structures in molecular- and nano-scale at our will, and try to find breakthroughs to drastically enhance the performance of the organic electronic devices. Targets of our research are not only the conventional organic solar cells and field-effect transistors, but also the organic electronic devices with new functions based on the structure controls.
Energetic driving force for charge generation in organic solar cells
For further improvement of the device performance of organic solar cells, optimization of electron-donating material and electron-accepting material is necessary. However, we first need to know the most suitable electronic structures for these materials. The problem was the lack of knowledge on the relation between the energetic driving force at the donor and acceptor interface and resulting device performance. To investigate the relationship between the interfacial energetic driving force and resulting device performance, the planar-heterojunction structures with simple and well-defined interfaces of electron-donating material (D) and electron-accepting material (A) are investigated. 16 planar-heterojunctions with four donor materials and four acceptor material were systematically investigated. We found that for efficient charge generation, molecularly excited state (S1) and interfacial charge-transfer (CT) state must have an energetic difference of 0.2~0.3 eV. This result provides a valuable guideline for the molecular design for efficient organic solar cells.
The charge generation efficiency is plotted against the energetic difference between the singlet excited state and charge-transfer state.
Crystallization of organic semiconductor in thin film induced from surface
Highly ordered crystalline thin films are required for organic electronics devices such as organic field effect transistors and organic photovoltaics. Rather complicated dynamic approaches have been reported to obtain large crystalline domains in solution-processed films. The interactions between the molecules and the substrate surface also play an important role in controlling the crystal structures and their orientation in thin films, known as template (or epitaxial) growth, but its application is mostly limited to evaporated films.
We discovered that self-assembled surface segregated monolayers can induce the crystallization of organic semiconducting materials in thin film from the surface. An unprecedentedly highly crystalline film of a methanofullerene derivative is formed simply by heating the film after spin-coating. The crystal structure induced by the surface was completely different from the known structure for the compound and oriented in the direction of the film normal. Owning to the high crystallinity, the electron mobility in the vertical direction was about five times higher than in the ordinally multicrystalline films. This new concept paves the way for enhancing the performance in various organic electronic devices.
(left) X-ray diffraction pattern of the fullerene derivative in thin films after crystallized from the surface and (right) the crystal packing structure obtained from the pattern.
Reproduced with permission. Copyright 2018, Wiely-VCH. DOI: 10.1002/anie.201801173
Organic semiconductors with proton-hopping promise
